Question:

A buffer solution - HNO2/NH3?

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How can weak acid nitrous acid HNO2 form a buffer solution with equal concentrations and volumes with weak base NH3?

I thought that buffer solutions only occured between weak acids and strong bases or vice versa. The example above as two weak soltuions.

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  1. A buffer solution usually consists of a mixture of a weak acid and its conjugate base.

    But in this case there are simply an acid and a base that don't react much with each other that each react with H+ or OH-

    The equilibrium for this reaction lies far to the left

    NH3 + HNO2 <==> NH4+ + NO2-

    The addition of H+ will cause this reaction:

    NH3 + H+ <==> NH4+

    The addition of OH- will cause this reaction

    HNO2 + OH- <==> HOH + NO2-

    So this mixture could be considered a crude buffer solution.

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