Question:

A cell exhibits a standard emf of +0.177 V at 298 K?

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What is the value of the equilibrium constant for the cell reaction in each of the following cases?

n=1

n=2

n=3

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  2. We know that

    Eo = (RT/nF)lnK

    Eo = voltage of cell = 0.177

    R= 8.314 JK-1mol-1 <-- constant

    T = temperature in Kelvins = 298K

    n = 1, 2, or 3, depending on your question

    F = 96500 J mol-1

    K = ??? <-- you want to solve for this

    Plug and chug away.

    E.g.: for n=2...

    Eo = (RT/nF)lnK

    0.177 = [(8.314*298)/(2*96500)]lnK

    0.177 = 0.0128371606 lnK

    13.78809576 = lnK

    e^(13.78808576) = K = 9.7E5

    Do the same for n=1 and n=3.

    [Answer: see above]

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