Question:

A solution in equilibrium with solid barium phosphate is found to have a barium ion concentration of?

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5 x 10^ -4 mol/L and a Ksp of 5 x 10^-23. Calculate the concentration of phosphate ion.

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  1. Ba3(PO4)2 -----  3 Ba+2 + 2 PO4^-3

    since a Ksp is equal to the concentrations of the products raised to the power of their coefficients  then

    Ksp = [Ba+2]^3 [PO4]^2

    so   (5 X 10^-4 )^3( PO4)^2 = 5 X 10^-23

    (PO4)^2 = 5 X 10^-23 / 125 X 10 ^-12

    PO4 ^-3 = 6.32 X 10^-7 M

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