Question:

Calculate Delta H and Delta S (1 of 3)

by Guest33684  |  earlier

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Calculate delta H and delta S for the following reaction and predict whether the reaction is either: always product favored, product favored at only at low temperatures, product favored only at high temperatures, or never product favored.

C6H12O6 (s) 6 O2 (g) ====> 6 CO2 (g) 6 H2O (l)

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  1. C6H12O6 (s)

    dHf = -1273.02 kJ

    S = 212.1J

    6 O2 (g

    dHf = 0

    S = (6) (205 J) = 1230J

    6 CO2 (g

    dHf = (6) (- 393.5) = -2361kJ

    S = (6) (213.6J) = 1281.6J

    6 H2O (l)

    dHf = (6)(-285.83)= -1714.98 kJ

    S = (6) (69.91) = 419.46J

    ===========================

    C6H12O6 (s)&   6 O2 (g) ====> 6 CO2 (g) &   6 H2O (l)

    dH = prod - reactants

    dH = ( -1714.98  & -2361 ) - (0  &    -1273.02 kJ)

    Your answer: dH = - 2802.96 kJ

    dS = prod - reactants

    dS = (419.46 & 1281.6J) - (1230  & 212.1J )

    your answer is: 258.96 J

    with needing a dG = - to be spontaneous,

    & dG = dH -TdS

    your answer is: product favored always product favored,

    & that is because the dH prodides the desired "-",  and at any temp,

    -TdS will always provide a "-"  

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