Question:

Calculate the density of oxygen gas at 25deg.C and 763 mmHg?

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I can get as far as changing from C to K... so 298.15 K =T and P=763mmhg =763 torr(1atm/760torr)=1.004

But now I don't know the steps to get the density. Please help! Thank you!

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  1. Ok assuming O2 is ideal then at 100 kPa and 298 K 1 mole occupies 24.8 dm3. Your pressure is slightly more than 100 kPa (1 bar) so the volume will be reduced to 24.38 dm3.

    1 mole for oxygen is 32 g so the density (mass/volume) = 1.31 g dm-3.


  2. Take the ideal gas law and rewrite n (moles) as m/Mm (mass in grams / molar mass).

    PV = (m / Mm)RT . . .multiply both sides by Mm

    PVMm = mRT . . . . . divide both sides by V

    PMm = (m/V)RT . . . but m/V = density (d)

    PMm = dRT

    d = PMm / RT = (1.004)(32) / (0.0821)(298.15) = 1.31 g / L

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