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Ea=59kJ/mol, how many times will the rate of the reaction increase when body temp goes from 37C-40C?

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Ea=59kJ/mol, how many times will the rate of the reaction increase when body temp goes from 37C-40C?

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  1. The dependency of rate of reaction is determined by the dependency of the rate constant on temperature. (for small temperature changes)

    Arrhenius equation relates rate constant to temperature as:

    k = A · exp( - Ea / (R · T) )

    So the ratio of rate constants (and the reaction rates) at two different temperatures is:

    k₂/k₁ = [ A · exp( - Ea / (R · T₂) ) ] / [ A · exp( - Ea / (R · T₁) ) ]

    = exp( - Ea / (R · T₂) ) / exp( - Ea / (R · T₁) ) ]

    = exp(  (Ea/R) · (1/T₁ - 1/T₂) )

    For

    Ea = 59kJ/mol

    T₁ = 37°C = 310K

    T₂ = 40°C = 313K

    k₂/k₁ = exp(  (59000J/mol / 8.314472J/molK) · (1/310K - 1/313K) )

    = 1.245

    So rate of reaction increases by about 25%


  2. ask this under chemistry, not physics!

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