Question:

Find the molarity of KOH solution with a pH of 9.5?

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help please....explain very well

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  1. pH+pOH = 14

    pOH = 14-pH

    pOH = 14-9.5

    pOH =4.5

    [OH] = 10^-pOH

    [OH] = 10^-4.5

    [OH] = 3.1623*10^-5

    KOH <=> K+  +  OH-

    Because molar concentration OH- = molar concentration KOH,

    Therefore molar conc KOH = 3.1623*10^-5M


  2. This is the chemical equation that describes this solution

    KOH --> K+ + OH

    Recall that pH = -Log[H3O+]

    [OH-][H3O+] = kw

    kw is the autoprotolysis of water constant and its equal to 1 x 10^-14

    since we know the pH we can solve for [H+] (an abbreviation for the hydronium ion (H3O+))

    pH = -Log[H+]

    9.5 = -Log[H+]

    recall that n = 10^a means that logn = a

    -9.5 = Log[H+]

    10^-9.5 = [H+]

    [H+] = 3.16227766 x 10^-10 M

    now use the autoprotolysis of water equation to find the concentration of  hydroxide ion (OH-):

    [H+][OH-] = 1 x 10^-14

    [OH-] = (1 x 10^-14)/[H+] = (1 x 10^-14)/(3.16227766 x 10^-10 M) = 3.1623 x 10^-5 M

    Since KOH is a strong base the concentration of OH- is the same as the concentration of KOH, which is 3.1623 x 10^-5 M.

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