Question:

Find the number of waters of hydration (x) in the hydrate.

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A hydrate of copper (II) chloride has the following formula:

CuCl_2 *xH_2 O.

The water in a 3.41 g sample of the hydrate was driven off by heating. The remaining sample had a mass of 2.69 g.

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  1. Actually

    CuCl2 x 2H2O.


  2. Calculate the mass of water, the mass of anhydrous salt remaining, convert those to moles, and calculate the mole ratio of water to anhydrous salt.

    Mass H2O = 3.41 - 2.69 = 0.72 g

    Mass anhydrous CuCl2 = 2.69 g

    moles H2O = 0.72 g H2O x (1 mole H2O / 18.0 g H2O) = 0.040 moles H2O

    moles anhydrous CuCl2 = 2.69 g x (1 mole CuCl2 / 134.5 g CuCl2) = 0.020 moles CuCl2

    moles H2O / moles CuCl2 = 0.040 / 0.020 = 2  so x = 2

    The formual of the hydrate is CuCl2 x 2H2O.

  3. at wt of Cu=63.5

    Cl=35.5

    2CL=70

    dehydrate CuCl2weigh= 63.5+70=133.5g

    2.69gm CuCL carried (3.41-2.69)gm OR 0.72gm water

    1gm carried 0.72/2.69=0.2676 gm

    133.5 gm carrying  133.5*0.2676 or35.72  or approx  36 Gm

    therefore  2 molucles of H2O  or 36gm carried by CuCl2

    x=2 ans

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