How did scientists realized the existense of the ozone layer?

Question

Has the invention of the airplanes played a part on it?

Answer 1

Many say that once we punctured the atmosphere with spaceships the ozone began to dissappear. I am not sure how scientists discovered that it exists or that it is shrinking.

Answer 2

The photochemical mechanisms that give rise to the ozone layer were worked out by the British physicist Sidney Chapman in 1930. Ozone in the earth's stratosphere is created by ultraviolet light striking oxygen molecules containing two oxygen atoms (O2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O2 to create ozone, O3. The ozone molecule is also unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O2 and an atom of atomic oxygen, a continuing process called the ozone-oxygen cycle, thus creating an ozone layer in the stratosphere, the region from about 10 to 50 km (32,000 to 164,000 feet) above Earth's surface. About 90% of the ozone in our atmosphere is contained in the stratosphere. Ozone concentrations are greatest between about 20 and 40 km, where they range from about 2 to 8 parts per million. If all of the ozone were compressed to the pressure of the air at sea level, it would be only a few millimeters thick.

Ten percent of the ozone in the atmosphere is contained in the troposphere, the lowest part of our atmosphere where all of our weather takes place. Tropospheric ozone has two sources: about 10 % is transported down from the stratosphere while the remainder is created in smaller amounts through different mechanisms.

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