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How does Phenolphthalein acid base indicator work...and in what titrations should it be used for?

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How does Phenolphthalein acid base indicator work...and in what titrations should it be used for?

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  1. It changes pink when the acid becomes a base.

    Acid-base titration.


  2. Phenolthalein is a weak acid. Let us call it HPh. When you add  a solution of HPh to an acidic solution, the acid HPh does not ionise. Because the HPh molecule is colourless, the acidic solution is colourless. If yo now add a solution of a base (as in a titration) when all the acid has been neutralise, the HPh is able to dissociate

    HPh <=> H+  +  Ph-

    The Ph - ion is bright pink in clour, so the base solution becomes pink in colour. The ionisation of the HPh occurs at a pH above 8.3. The indicator is therefore used to titrate a strong base with a strong acid.

    I have a very good paper on the chemistry of indicators. If you send me a contact email address I will forward to you.

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