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I can't do this chemistry!?

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Aqueous ammonia is added to Cu2+ and a precipitate is formed. If further addition of aqueous ammonia to the solution dissolves the precipitate, what happened and what is the product?

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  1. Ammonia reacts with water to form a basic solution:

    NH3 + H2O ----> NH4+ + OH-

    Because cupric hydroxide is insoluble, the hydroxide ion will precipitate with the Cu2+ ion:

    Cu2+ + 2OH- ----> Cu(OH)2

    Adding more ammonia leads to the formation of a complex ion, which in this case is soluble.  It will form a dark blue solution:

    Cu(OH)2 + 4NH3 ----> [Cu(NH3)4]2+ + 2OH-

    The link provides some more info on complex ions.

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