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Nitrogen is diatomic but phosphorus is tetra-atomic. Why?

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Nitrogen is diatomic but phosphorus is tetra-atomic. Why?

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  1. Due to larger atomic size P is unable to form pi bonds and so it is tetra-atomic in which each P atom is linked with 3 other P atoms by 3 sigma bond.But, due to smaller atomic size N forms 1 sigma and 2 pi bonds i.e. triple bonds with other N atom and exists as diatomuc molecule.


  2. I don't know the basic reason, but, 2 nitrogen atoms form di-nitrogen atom by triple bonding.

    While in case of phosphorus, 1 P atom is linked to 3 other P atoms by a single bond.

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