Question:

On using boiled HNO3 in comparing AgNO3 and KSCN solutions?

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a solution containing AgNO3, distilled water and recently boiled 6N HNO3 is titrated with KSCN solution (indicator is ferric alum). why is it necessary to use boiled HNO3?

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  1. Boiling HNO3 removes dissolved NO2.

    This would complex with the Fe3+ ions.

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