Question:

Please help: If 542 microLiters of 0.0402 M KMnO4 are required to titrate 200 microLiters of NaI solution...?

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...to the endpoint in acid, what was the concentration of Iodide ion in the original solution?

Any help will be appreciated! Thank you.

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  1. M1V1=M2V2

    200*(?) = 542*0.0402

    this gives you molarity of NaI - 0.108M

    NaI is built of Na = 23g and I of 127 gms totalling 150 gms.

    So your 0.108 molar solution has 15 gms of NaI.

    now, 150 gms NaI contains 127 gms of I

    than 15 gms contains = 15*127/150 = 12.7 gms I in liter.

    1liter = 1000ml = 1000000 ul contains 12.7 gms I

    than 200 ul contains = 200*12.7/1000000= 2.54x10^-3

    ANS = 2.54x10^ -3

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