Question:

Predict the cell potential for the following rxn when the P O2(g)= 2.50 atm, [H+]= 0.1M, [Br] 0.26M?

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O2(g)+4H+(aq)+4Br(aq)-->2H2O(l)+2Br2(l)

E^0 of cell=0.152V

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  1. nernst:

    E = Eo - (0.0592/n)log Q

    E = 0.152  - (0.0592/4 mol e-) log prod / reactant

    E = 0.152  - (0.0148) log 1 / [O2] [H+]^4 [Br-]^4

    E = 0.152  - (0.0148) log 1 / [2.5] [0.1]^4 [0.26]^4

    E = 0.152  - (0.0148) log 1 / 1.14e-6

    E = 0.152  - (0.0148) log 875319

    E = 0.152  - (0.0148) 5.942

    E = 0.152  - 0.088

    your answer is: E = 0.064 volts

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