Question:

So confused... empirical and molecular formulas?

by Guest32276  |  earlier

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compound contains only C, H, and N. Combustion of 42.0 mg of the compound produces 40.2 mg CO2 and 49.3 mg H2O. What is the empirical formula of the compound?

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  1. Moles CO2 = 0.0402 g/ 44.0098 g/mol =0.000913

    Mass C = 12.011 g/mol x 0.000913 mol = 0.0110 g

    Moles water = 0.0493 g / 18.02 g/mol = 0.00274

    Moles H = 2 x 0.00274 = 0.00548

    Mass H = 0.00548 mol x 1.008 g/mol =0.00552 g

    Mass N = 0.042 - ( 0.0110 + 0.00552) = 0.0255 g

    Moles N = 0.0255 / 14.0067 g/mol = 0.00182

    C (0.000913) H ( 0.00548) N ( 0.00182)

    we divide by the smallest number to get the empirical formula

    0.000913/ 0.000913 = 1 => C

    0.00548/ 0.000913 = 6 => H

    0.00182 / 0.000913 = 2 => N

    CH6N2

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