Question:

The energy levels of a particle in a 1-d box?

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The energy levels of a particle in a 1-d box are given by E=n^2h^2/8mL. As the length of the box gets larger:

a) the energy difference between n=1 and n=2 gets larger

b) the energy difference between n=1 and n=2 gets smaller

c) the energy difference between n=1 and n=2 stays constant

d) it will require more energy to excite the particle from n=1 to n=2

Note: more than 1 answer may be right

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2 ANSWERS


  1. As L increases, E decreases proportionately.

    b, and d.

    Edit: I believe option d is poorly stated and should be challenged. If distance is increased, more energy would be require.  

    Humans write test questions, and we all make mistakes :-).


  2. There's a mistake in your formula, it should read n^2 h^2 / 8mL^2 - remember that the L is squared.

    Anyways, the energy of the level n = 1 is given by

    h^2 / (8mL^2)

    and that of the level n = 2 is then

    4h^2 / (8mL^2)

    Therefore, the energy difference is

    3h^2 / (8mL^2)

    so that as L increases, this difference decreases - i.e, choice b) is correct. Choice d) is equivalent to choice a), so it is not correct.

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