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What are the conditions in which the Beer-Lambert law fails?

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What are the conditions in which the Beer-Lambert law fails?

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  1. aSK A lawyer


  2. beer never fails.

  3. This usually occurs when the concentration of the the absorbing material becomes too high. Normally absorbance and concentration are proportional until the absorbance gets to be over about 1 unit. After that the curve begins to flatten so that doubling the concentration gives an absorbance of less then double the original value.
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