Question:

What organ does alcohol effect first?

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liver
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probably your kidneys and liver since many alcoholics usually develope kidney/liver disease/cancer.
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Alcohol speeds damage to the liver then to the kidney.besides liver has higher place than the kidney.
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The Liver.

But overall the liver, the kidneys, and the brain.

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I think it depends on the person I know a women that had her heart fail from it and her liver was fine. It pickled her heart so to speak,
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Alcohol is broken down by the stomach and can be absorbed by blood vessels in the stomach and can reach the brain within one minute.

So the Brain is the first organ it affects.

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The Liver.
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Effect? Meaning, have a relevant effect on? The brain. If you hurry, you can down three shots in ten seconds, and feel the effect almost immediately...in your brain. The liver hasn't even begin to metabolize the EtOH yet.
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Liver & Kidneys..
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I believe the answer to your question is the brain. Over time the liver and kidneys will be damaged but when you drink alcohol your brain is effected first. That is why people drink it.
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