Question:

What would the delta Hvap be for a substance whose vapor pressure doubled when its temperature was raised?

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from 70.0 centigrade to 80 degree centigrade?

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  1. ln(P2/P1) = (∆Hvap/R) (1/T1 - 1/T2)

    ln(2/1) = ∆Hvap / (8.314 J/K-mol) (1/343 K - 1/353 K)

    Solving, ∆Hvap = 69,780 J/mol or about 70 kJ/mol.

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